Plan Tech, Inc. Last Revision Date: 9 September 2015
Polyurethane Elastomer Safety Data Sheet (SDS)
1. Identification
1.1 Product identifier Polyurethane Elastomer
1.2 Relevant uses and uses advised against For industrial or professional use only.
1.3 Details of the supplier of the safety data sheet
1.4 Emergency contact information Call 603-783-4767
Plan Tech, Inc.
7031 Shaker Road
Loudon, NH 03307
603-783-4767
2. Hazard(s) Identification
2.1 Classification of the substance or mixture. While this material is not considered hazardous according to the OSHA Hazard Communication Standard (29CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available.
2.2 Label elements
Hazard statements and symbols/Precautionary statements: None
2.3 Other hazards
Emergency Overview
Acute: Fumes from hot work on or near polyurethane products can be irritating and lead to coughing. These fumes could contain traces of TDI, and/or MBOCA. Skin or airborne exposure to isocyanates may produce an asthma-like lung sensitization, with shortness of breath, wheezing or cough, which may occur after re-exposure to very low levels. Skin contact with some polyurethane products may result in skin sensitization or an asthma-like
lung sensitization. Chronic: Animal studies indicate that chronic inhalation or overexposure of dusts may cause inflammation of the lungs, fibrosis, and airway destruction.
Severe Immediate Hazards
Dusts from grinding operations may aggravate existing lung disorders when proper protection is not used.
OSHA Regulatory Status
POLYURETHANE ELASTOMERS ARE FULLY REACTED POLYMERS FORMING ARTICLES WHICH ARE NOT CONSIDERED HAZARDOUS UNDER OSHA’s CRITERIA 29 CFR 1910.1200. HOWEVER, HAZARDOUS DUSTS, VAPORS, GASES, OR FUMES MAY BE RELEASED BY MECHANICAL OR THERMAL PROCESSING, OR BY
THERMAL DECOMPOSITION.
3. Composition/Information on ingredients
Component Synonyms CAS# Concentration (wt%) Cast polyurethane n/a >99.9% 4,4’ methylene bis (2-chloroaniline) MBOCA or MOCA 104-14-4 <0.1%
4. First aid measures
4.1 Description of the first aid measures
Route of Exposure Instructions
Inhalation Move to an area free from the risk of further exposure. If not breathing, or breathing is difficult, obtain medical attention. Eye Contact If dust from grinding causes irritation, rinse with water immediately for 5
minutes. Seek medical attention if irritation persists. Skin Contact Wash exposed skin with soap and water. Ingestion Not a route of exposure.
4.2 Most important symptoms and effects, both acute and delayed
Acute: None
Delayed: Sensitizing effects possible from dusts/fumes
4.3 Indication of any immediate medical attention and special treatment needed. No antidotes known
5. Fire Fighting Measures
5.1 Extinguishing media
Suitable media includes carbon dioxide, dry chemical, foam, or water spray.
5.2 Special hazards arising from the substance or mixture
Toxic and/or irritating fumes can be produced during burning of this material.
Decomposition products may be hazardous (see section 10 for details on decomposition
products).
5.3 Advice for Firefighters
Firefighters should wear self-contained breathing apparatus and full protective clothing.
Downwind personnel should be evacuated. Do not reseal contaminated containers as pressure buildup may rupture them.
6. Accidental Release Measures
6.1 Personal precautions, protective equipment, and emergency procedures
Evacuate personnel. Wear suitable PPE as described in section 8.
6.2 Environmental precautions
No environmental precautions required.
6.3 Methods and materials for containment and cleaning up. Pick up and handle as any other solid material.
7. Handling and Storage
7.1 Precautions for safe handling. None in normal use.
7.2 Conditions for safe storage, including anything that is incompatible. Store material at ambient temperature and pressure. Keep away from sources of flame, sparks, or other ignition sources. Material is stable under normal conditions.
7.3 Specific end use(s) No specific requirements needed
8. Exposure Controls/Personal Protection
8.1 Control parameters
Permissible Exposure Limits (PELS TLVs BEIs). There are no applicable exposure limits for cured polyurethane materials. There are limits for TDI and MDI which may be released under some heat processing activities.
The current OSHA Permissible Exposure Limit for both TDI and MDI is 0.02 ppm (Ceiling). A ceiling limit is not to be exceeded. The current American Conference of Governmental Industrial Hygienists (ACGIH). Threshold Limit Value (TLV)for TDI is 0.005 ppm for an 8 hour TWA, with a 15 minute Short Term Exposure Limit (STEL) of 0.02 ppm. TDI is also indicated as a “Sensitizer” by ACGIH. The 8 hour TLV for MDI is 0.005 PPM TWA. The TLV for TDI is under the 2006 ACGIH notice of intended changes. The proposed change is to lower the TLV for TDI to
0.001 ppm for an 8 hour TWA, with a 15 minute STEL of 0.003 ppm. The proposal for TDI also recommends adding a “Skin” notation and making the cancer designation “A3 – Confirmed Animal Carcinogen with Unknown Relevance to Humans”.
8.2 Exposure controls
Engineering Controls:
Local exhaust recommended for thermal processing operations, as required to rethermal processing operations (including potentially some grinding operations) wear a NIOSH approved air-purifying respirator with organic
cartridge or supplied-air respirator if ventilation is inadequate. Replace cartridge according to respirator manufacturer’s changeout schedule.
9. Physical and Chemical Properties
Property Value Property Value
Appearance Solid Odor None
Odor Threshold N/A pH N/A
Melting/Freezing Pt. >150°C (302°F) Initial Boiling Pt./Range N/A
Flash Pt. N/A Evaporation Rate N/A
Flammability
(solid, gas)
Dusts from processing operations may be combustible Upper/Lower Flammability Limits or Explosive Limits
N/A
Vapor Pressure N/A Vapor Density N/A
Relative Density ~1.0-1.3 (23°C/73°F) Solubility(ies) Not soluble in water
Partition Coefficient: noctanol/water N/A
Auto-ignition Temperature N/A
Decomposition Temperature >150°C (302°F) Viscosity (Dynamic) N/A
10. Stability and Reactivity
10.1 Reactivity Not reactive under normal use.
10.2 Chemical Stability Stable under normal use/storage conditions.
10.3 Possibility of hazardous reactions No dangerous reactions will occur under normal
use/storage conditions.
10.4 Conditions to avoid Exposure to extreme temperatures and contact
unwanted contact with incompatible materials
should be avoided.
10.5 Incompatible materials Strong acids or bases.
10.6 Hazardous decompositions products
Decomposition through burning produces fumes consisting of organic particulate, gaseous
hydrocarbons, carbon dioxide, carbon monoxide and may contain traces of toluene
diisocyanate (TDI) or diphenylmethane diisocyanate (MDI), other isocyanates, MBOCA,
hydrogen cyanide, acrolein, and oxides of nitrogen.
11. Toxicological Information
11.1 Information on toxicological effects
Acute Toxicity (product): No data available on product.
Skin and eye corrosion/irritation (product) No data available on product.
Sensitization (product): No data available on product.
Mutagenicity: No data available on product.
Carcinogenicity: No data available on product.
Reproductive Toxicity: No data available on product.
STOT-SE: No data available on product.
STOT-SE (toluene diisocyanate): Respiratory Tract Irritant
STOT-RE: No data available on product.
Aspiration: Not an aspiration hazard
12. Ecological Information
12.1 Toxicity Not applicable under normal conditions.
12.2 Persistence and degradability Product is not expected to rapidly biodegrade.
12.3 Bioaccumulative potential No data available on product.
12.4 Mobility in soil No data available on product.
13. Disposal Considerations
13.1 Waste treatments methods
Follow all applicable local, state, and federal disposal regulations.
14. Transport Information
14.1 UN number: Not regulated
14.2 Proper shipping name: Not regulated
14.3 Hazard class: Not regulated
14.4 Packing group: Not regulated
14.5 Environmental hazards: Not regulated
14.6 Special precautions for the user: Not regulated
14.7 Transport in bulk information: Not regulated
15. Regulatory Information
15.1 Safety, health, and environmental regulations/legislation specific for the substance or mixture
TSCA Health & Safety Reporting List: N/A
Chemical Test Rules: N/A
Section 12b: N/A
TSCA Significant New Use Rule: N/A
CERCLA Hazardous Substances and corresponding RQs: N/A
SARA Section 302 Extremely Hazardous Substances: N/A
SARA Codes: N/A
Section 313: N/A
Clean Air Act: N/A
Clean Water Act: N/A
U.S. State Regulations California Prop 65: N/A
Other States: N/A
International Regulations European/International Regulations N/A
Canada DSL/NDSL: N/A
WHMIS: N/A
15.2 Chemicals safety assessment No data available
16. Other Information
SDS Creation Date: 29 May 2015
Abbreviation key:
PEL – permissible exposure limit
TWA – time-weighted average
TLV – threshold limit value
STEL – short-term exposure limit
IDLH – immediately dangerous to life and health
OSHA – Occupational Safety and Health Administration
ACGIH – American Conference of Governmental Industrial Hygienists
NIOSH – National Institute for Occupational Safety and Health
N/A – Not applicable LC50 – lethal concentration to 50% of test subjects
LD50 – lethal dose to 50% of test subjects
STOT-SE – Specific target organ toxicity (single exposure)
STOT-SE – Specific target organ toxicity (repeated exposure)
EC50 – effective concentration that causes 50% of response from test subjects
ErC50 – EC50 in terms of growth rate reduction
CERCLA – Comprehensive Environmental Response, Compensation, and Liability Act
SARA – Superfund Amendments and Reauthorization Act
TSCA – Toxic Substances Control Act (N)
DSL –(Non-) Domestic Substances List
WHMIS – Workplace Hazardous Materials Information System
Note: This safety data sheet is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. It is not meant to be an all-inclusive document on worldwide hazard communication regulation. This information is believed to be accurate as of the date issued. Each user of this material needs to evaluate the conditions of use and design the appropriate protective mechanisms to prevent exposures, property damage, or release to the environment. No warranty is expressed or implied with respect to the information herein supplied, and no responsibility for injury to the recipient or third persons, or for any damage to any property is assumed.
